There's a Hilton connected by walkways to the airport, but it's pricey. There are other less expensive hotels in the airport area, but their shuttles don't operate that early and local (Fiumicino) cabs are comparatively expensive.

Your best bet is really to spend the last night in central Rome and reserve a car service for the ride to the airport. For three people, it would cost 40 Euro with www.romeshuttlelimousine.com - not that much more than the 33 Euro it would cost with the Leonardo Express if it were operating that early.

If it's a flight within Europe, I'd suggest you get there 1.5 hours before your flight. The trip to the airport shouldn't take more than 30 minutes, barring accidents.

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