Florence is IN Tuscany
Arezzo is 40 minutes away by train.
The best web site for investigating cross-border train journeys is run by the German railways: reiseauskunft.bahn.de/bin/query.exe/en?
You will need to travel by the Swiss railways to Milan, then by Italian railways.
Swiss trains: www.sbb.ch/en
Italian: www.trenitalia.com clicking on the UK flag to change to English and using the Italian names for towns
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