It's probably the best idea to use GoOpti's shuttle. Taking a train would take unreasonably long.
Thanks for your recommendation using
GOOPTI..how many persons in van?.Assume they stop for breaks..eric
try to fly to Trieste its closer...but yes it is a cca 5h train ride to Trieste from Milan, than you can take another train to Ljubljana. Don`t know how you like an idea to rent a campervan in Slovenia and visit TOP places. if u like to camp, than try Marley Campervan, https://www.facebook.com/marleycampervan its a new, small family bussines.
take care M
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