take a look here
You have it at 06:00, 09:00, 11:00, 15:00, 18:15.
It looks like train#720 picks you up at 7:07AM, or train #722 departs at 7:12PM.
I highly recommend the train. It is dirty and grimy, but the most beautiful train ride I have ever been on. It was a a great adventure I will never forget. It is also dirt cheap. No need to book beforehand. And I would also suggest "upgrading" to first class.
Buses are frequent, you can expect every hour during working day. Trains are less frequent, maybe 1 or 2 per day but very scenic route.
buses are quite frequent. we took the 7.07 am train from mostar to sarajevo last week. ticket by on the day of travel. they refused to sell the ticket even a day earlier. the view was stunning. i would recommend the train. the journey took nearly 3 hours
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