The Sunflower guide gives directions for walking from Maiori to Santa Maria de Olearia which makes a wonderful excursion (though you could drive). The walk takes you high above the coast and then you descend to this little chapel which is on 3 levels, each of which gets progressively more richly frescoed and delightful as you ascend. The opening times are rather limited so you should check at the tourist office for times.
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